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Has anyone had experience with using alkaline battery instead of Li-Po? I am trying to figure out whether to put 2 in serial (3V) or 3 in serial (4.5V).
Are you trying to put them in place of the Li-Ion place?
If yes, it should NOT be more than 4.2V in total but you should NEVER EVER plug in the USB or VIN when the battery is in place as it will charge the alkaline when you should not.
There is plan for a version for non-rechargeable batteries but no ETA at the moment. This allows people to use (and easily purchase) the battery off the shelf as Li-Ion/Pol has more restriction in air shipping.
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